You can add a border to a PowerPoint slide by adding a rectangle shape and removing the fill color, which will give the appearance of a border.
Your options for editing PowerPoint templates look fairly similar whether you make them on the desktop or web version of PowerPoint.
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How to Crop Pictures in Microsoft Word, Excel, and PowerPoint
To manually crop a picture in Microsoft Word, Excel, or PowerPoint, select it, and in the Picture Format tab on the ribbon, click the top half of the split "Crop" button.
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